I’m by no means an expert on this, but from my A level chemistry all those years ago I seem to remember that a buffered solution contained a compound that would stabilise the pH of a solution by freeing up or binding hydrogen ions. Clearly it is very important that blood stays at the right pH, so I don’t find it at all surprising that blood contains such buffering compounds.
I’m sorry I don’t know more about this subject – it sounds quite interesting.
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